Relaxor ferroelectric behavior of La substituted BPZT ceramics

Abstract

Barium titanate (BT) based compounds have been of great importance in the fabrication of multilayer ceramic capacitors. Several substitutions are used to tailor its structural, electrical and ferroelectric properties. Substituent like zirconium (Zr) for titanium results in decrease in non-centrosymmetric tetragonal to centrosymmetric cubic phase transition temperature (Curie temperature). Whereas substituent like lead (Pb) for barium results in the increase in the Curie temperature. Here we are reporting effect of lanthanum (La) substitution on the properties of Zr and Pb co-substituted BT. The system Ba<inf>0.80-x</inf>La<inf>x</inf>Pb<inf>0.20</inf>Ti<inf>0.90</inf>Zr<inf>0.10</inf>O<inf>3</inf> with x = 0 and 0.01 was selected for study of structural and dielectric properties. Samples were prepared using solid state ceramic route. X-ray diffraction studies (XRD) were used to confirm single phase structure. Dielectric properties were studied as a function of frequency and temperature. Composition with x = 0.01 was found to show relaxor behavior. © 2010 Elsevier Ltd and Techna Group S.r.l. © 2010 Elsevier B.V., All rights reserved.